Fuel cell comprising single layer bipolar plates, water damming layers and MEA of diffusion layers locally treated with water transferring materials, and integrating functions of gas humidification, membrane hydration, water removal and cell cooling

ABSTRACT

A fuel cell comprising single layer bipolar plates, water damming layers(WDL) and membrane electrode assembly (MEA) with gas diffusion layers(GDL) locally treated with water transferring materials, and integrating functions of gas humidification, membrane hydration, water removal and cell cooling is disclosed. This fuel cell is constructed with proton exchange membrane (PEM) and catalyst layers on both sides of PEM, with GDL, on top of catalyst layers, locally impregnated with water transferring materials, and single layer bipolar plates installed on both sides of GDL as cathode and anode. On one side of the plates, as anode, flow channels are structured for hydrogen rich reactant flow, capable of accommodating cooling water, and on the other side, as cathode, flow channels are structured for oxidant flow, capable of accommodating cooling water, with WDL treated with water transferring materials, placed between flow channels of cooling water flow and gas diffusion layers and in direct contact with said water on one side and said layers on the other.

TECHNICAL FIELD

This invention relates to a polymer fuel cell comprising single layer bipolar plates, water damming layers(WDL) and membrane electrode assembly (MEA) of gas diffusion layers(GDL) locally treated with water transferring materials, and integrating functions of gas humidification, membrane hydration, water removal and cell cooling.

BACKGROUND

A fuel cell in this invention refers to a polymer ion membrane fuel cell, “Proton Exchange Membrane fuel cell”, a device to generate power through Proton Exchange Membrane (PEM) and Catalyst Layers (CL). This fuel cell can generate power continuously as long as fuel (i.e. hydrogen) is available.

In the core of this PEM fuel cell technology, hydrogen molecular is catalyzed to decompose as proton and electron on one side of PEM called anode side, the proton goes through the PEM to the other side called cathode side, and the electron reaches cathode side through a load with power generated, where the hydrogen proton, electron and oxygen molecular fed directly to cathode side, combine together to be water molecular at cathode side. Therefore, in the fuel cell the hydrogen combines with oxygen to form water with electricity generated and such a process is also seen as reverse of water electrolysis, as shown in the following picture.

PEM is a kind of special material that can conduct proton but can't conduct electronics, it can be in effect only when it's hydrated and the ability of conducting proton is proportionate to the degree of hydration. Gas diffusion layer (GDL) is a porous material which directs reactant gas to the CL through the porous, so it is necessary to keep the porous path clear. It is a dilemma that on one hand enough water is needed to keep PEM hydrated, while on the other hand generated water must be removed to keep the GDL porous path clear. Therefore, one of the key technologies of PEM fuel cell is about water management.

One of the traditional solutions is to humidify reactant gas fed into fuel cells. Not only does this method complicate fuel cell structure, but also is incapable of controlling the humidification degree of the PEM and water removal, since the humidification process could feed more or less than enough water to flood or try cells, while generated water could make flooding worse if not removed effectively.

REFERENCE

U.S. Pat. No. 7,232,622 Jun. 19, 2007 Kim U.S. Pat. No. 7,229,711 Jun. 12, 2007 Breault U.S. Pat. No. 7,226,680 Jun. 5, 2007 Wexel, et al. U.S. Pat. No. 7,220,513 May 22, 2007 Rohwer, et al. U.S. Pat. No. 7,205,059 Apr. 17, 2007 Corey, et al. U.S. Pat. No. 7,201,992 Apr. 10, 2007 Yang, et al. U.S. Pat. No. 7,189,572 Mar. 13, 2007 Imamura, et al. U.S. Pat. No. 7,184,875 Feb. 27, 2007 Ferrall, et al. U.S. Pat. No. 7,179,557 Feb. 20, 2007 Breault U.S. Pat. No. 7,179,501 Feb. 20, 2007 Beckmann, et al. U.S. Pat. No. 7,172,827 Feb. 6, 2007 Scholta, et al. U.S. Pat. No. 7,163,199 Jan. 16, 2007 Tanaka U.S. Pat. No. 7,153,605 Dec. 26, 2006 Horiguchi, et al. U.S. Pat. No. 7,147,214 Dec. 12, 2006 Klett, et al. U.S. Pat. No. 7,118,820 Oct. 10, 2006 Nuttall, et al. U.S. Pat. No. 7,090,940 Aug. 15, 2006 Schrooten, et al. U.S. Pat. No. 7,087,337 Aug. 8, 2006 Trabold, et al. U.S. Pat. No. 7,087,328 Aug. 8, 2006 Shimanuki, et al. U.S. Pat. No. 7,078,117 Jul. 18, 2006 Mossman U.S. Pat. No. 7,067,216 Jun. 27, 2006 Yan, et al. U.S. Pat. No. 7,063,907 Jun. 20, 2006 Breault U.S. Pat. No. 7,037,612 May 2, 2006 Collins, et al. U.S. Pat. No. 7,037,610 May 2, 2006 Meissner, et al. U.S. Pat. No. 7,036,314 May 2, 2006 Hoffjann, et al. U.S. Pat. No. 7,018,732 Mar. 28, 2006 Cargnelli, et al. U.S. Pat. No. 6,994,267 Feb. 7, 2006 Hwang U.S. Pat. No. 6,989,206 Jan. 24, 2006 Drake U.S. Pat. No. 6,986,958 Jan. 17, 2006 Reiser, et al. U.S. Pat. No. 6,964,820 Nov. 15, 2005 Shimonosono, et al. U.S. Pat. No. 6,953,635 Oct. 11, 2005 Suzuki, et al. U.S. Pat. No. 6,936,361 Aug. 30, 2005 Kelley, et al. U.S. Pat. No. 6,926,983 Aug. 9, 2005 Brambilla, et al. U.S. Pat. No. 6,926,980 Aug. 9, 2005 Kato, et al. U.S. Pat. No. 6,924,051 Aug. 2, 2005 Meissner, et al. U.S. Pat. No. 6,916,571 Jul. 12, 2005 Grasso, et al. U.S. Pat. No. 6,893,754 May 17, 2005 Agar, et al. U.S. Pat. No. 6,893,708 May 17, 2005 Shen, et al. U.S. Pat. No. 6,869,709 Mar. 22, 2005 Shimotori, et al. U.S. Pat. No. 6,869,719 Mar. 22, 2005 Hatoh, et al. U.S. Pat. No. 6,866,952 Mar. 15, 2005 Corey, et al. U.S. Pat. No. 6,844,095 Jan. 18, 2005 Lim, et al. U.S. Pat. No. 6,835,480 Dec. 28, 2004 Dykeman, et al. U.S. Pat. No. 6,835,219 Dec. 28, 2004 Gittleman U.S. Pat. No. 6,833,207 Dec. 21, 2004 Joos, et al. U.S. Pat. No. 6,824,900 Nov. 30, 2004 DeFilippis U.S. Pat. No. 6,808,832 Oct. 26, 2004 Suzuki, et al. U.S. Pat. No. 6,794,077 Sep. 21, 2004 Yi, et al. U.S. Pat. No. 6,790,550 Sep. 14, 2004 Imamura, et al. U.S. Pat. No. 6,787,256 Sep. 7, 2004 Matsui, et al. U.S. Pat. No. 6,780,533 Aug. 24, 2004 Yi, et al. U.S. Pat. No. 6,779,351 Aug. 24, 2004 Maisotsenko, et al. U.S. Pat. No. 6,777,119 Aug. 17, 2004 Demissie, et al. U.S. Pat. No. 6,777,117 Aug. 17, 2004 Igarashi, et al. U.S. Pat. No. 6,770,390 Aug. 3, 2004 Golden, et al. U.S. Pat. No. 6,753,106 Jun. 22, 2004 Chow, et al. U.S. Pat. No. 6,737,183 May 18, 2004 Mazzucchelli, et al. U.S. Pat. No. 6,696,186 Feb. 24, 2004 Herdeg, et al. U.S. Pat. No. 6,686,084 Feb. 3, 2004 Issacci, et al. U.S. Pat. No. 6,670,062 Dec. 30, 2003 Rush, Jr. U.S. Pat. No. 6,660,423 Dec. 9, 2003 Neutzler, et al. U.S. Pat. No. 6,630,260 Oct. 7, 2003 Forte, et al. U.S. Pat. No. 6,579,637 Jun. 17, 2003 Savage, et al. U.S. Pat. No. 6,576,358 Jun. 10, 2003 Gebhardt, et al. U.S. Pat. No. 6,566,002 May 20, 2003 Yoshimoto, et al. U.S. Pat. No. 6,541,141 Apr. 1, 2003 Frank, et al. U.S. Pat. No. 5,958,613 Sep. 28, 1999 Hamada, et al. U.S. Pat. No. 5,503,944 Apr. 2, 1996 Meyer, et al.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 illustrates a cross sectional, schematic view of the fuel cell having two said single layer plates 1, with plurality of channels on both sides for reactant gas flows and cooling liquid flows, to sandwich water damming layers 6 (WDL) and a membrane electrode assembly (MEA) in between. A schematic view of the MEA is given with a membrane layer 4, two catalyst layers 3 and two gas diffusion layers (GDL) 2 with locally impregnated regions 5 corresponding to the liquid flow channels.

FIG. 2 a shows an enlarged cross-sectional, schematic view of one cooling liquid channel on the plate 1 in connection with WDL 6 and region 5 of GDL 2 of the MEA, both of which are treated with water transferring materials.

FIG. 2 b is mostly the same as FIG. 2 a, except the shape of the region 5 which goes deeper down in touch with catalyst layer 3.

FIG. 3 depicts a cross-sectional, schematic view of a single layer plate 1, a half MEA having catalyst layer 3, membrane 4 and gas diffusion layers (GDL) 2 with locally impregnated regions 5 to illustrate three different humidifying paths of the cooling liquid. One of them (Green) is to pass water into reactant flow channels; the second (Yellow) is to humidify reactant right in GDL; the third (Blue) is to deliver water into catalyst and membrane layers.

FIG. 4 illustrates a cross-sectional, schematic view of a single layer plate 1, a half MEA having catalyst layer 3 and gas diffusion layers (GDL) 2 with locally impregnated regions 5 to illustrate water removal principles. There are three paths to remove water generated in fuel cell. One of them (Red) is the traditional way to let the water go into reactant flow channels; the second (Magenta) is to let water move from GDL under reactant gas flow channels into WDL via the impregnated region of the GDL and then cooling liquid flow channels; the third is to let water move from catalyst layer into GDL under landing then directly into WDL and the impregnated regions of the GDL and then further into cooling liquid flow channels (Cyan).

DISCLOSURE OF THE INVENTION

In accordance with the present invention, there is provided a novel design of a fuel cell constructed with single layer bipolar plates, membrane electrode assembly (MEA) with gas diffusion layers (GDL) locally impregnated with water transferring materials (e.g. nafion, etc.), and/or water damming layers (WDL) also treated with water transferring materials. While the fuel cell integrates reactant gas flow fields on both sides of the plates, upon different needs, humidifying, hydrating and cooling water (HHCW) flow fields can be placed on one side or both sides of the single layer plates to achieve functions of gas humidification, membrane hydration, water removal and cell cooling. One of embodiments features the fuel cell constructed with the WDL and locally impregnated GDL stacked together directly in contact with the HHCW flow channels of the plates on one side (WDL side) and catalyst/membrane layers on the other (GDL side), another embodiment has the locally impregnated GDL, without WDL, directly placed underneath the HHCW flow channels of the plates, and another embodiment has WDL placed between the HHCW flow channels and MEA with regular GDL without local treatment for water transport.

In reference to FIG. 1, there is shown a cross sectional, schematic view of the fuel cell having single layer plates 1 fabricated with plurality of reactant (air) flow channels, and HHCW flow channels on one side, and reactant (fuel) flow channels and HHCW flow channels on the other side, and between two plates sandwiched a membrane electrode assembly (MEA) which has catalyst layers 3, membrane 4 and GDL 2 fabricated with local regions 5 impregnated with hydrophilic and water transferring materials, and between regions 5 of GDL 2 and the HHCW flow channels placed with WDL 6 that are also porous medium treated with hydrophilic and water transferring materials, as shown in FIGS. 2 a and 2 b, so water permeability of the WDL 6 and region 5 is well designed along with certain controlled contact gaps between plates 1, WDL 6 and region 5 to allow required liquid (water) to pass through both ways in or out the HHCW flow channels under adjustable and given pressure difference between HHCW flow channels and reactant flow channels, as shown in FIG. 3 and FIG. 4, to achieve functions of humidifying reactant gases, hydrating membrane, removing excessive water.

FIGS. 2 a and 2 b give a closer and enlarged cross-sectional, schematic view of one HHCW flow channel on plate 1 and the porous WDL 6 and the impregnated region 5 of GDL 2 of MEA. Plate 1, WDL 6 and MEA with region 5 on GDL 2 are assembled together to achieve and integrate functions of humidifying gases, hydrating membrane, cooling cells and removing water generated in the fuel cell.

As indicated in FIG. 3, not only do liquid flows in the HHCW flow channels act as a cell cooling means, but also provide humidifying water, a part of which flows through WDL 6 into reactant flow channels, as shown by green arrows, where the water becomes a local source for reactant gas humidification in the reactant gas flow channels, a part of which goes through WDL 6 and region 5 of GDL 2, also into other parts of GDL 2, as shown by yellow arrows, where the water is to humidify reactant flow right in the GDL 2 porous medium, and a part of which penetrates WDL 6 and region 5 of GDL 2 into catalyst layer 3 and membrane layer 4 as a source to hydrate membrane, as shown by blue arrows.

As indicated in FIG. 4, in additional to a traditional way to have excessive water generated in electrochemical reaction removed through the reactant flow channels on plate 1, as shown by red arrows, this invention provides a novel means of water removal that by taking advantage of capillary force formed in the porous media WDL 6, region 5 and GDL 2, and by adjusting pressure difference between the HHCW flow channels and reactant gas flow channels, a portion of the excessive water accumulated in region 5 of GDL 2 and WDL 6, due to hydrophilic and water transferring nature of the materials used in region 5 and WDL 6, can be driven into the HHCW flow channels for removal, as shown by magenta and cyan arrows.

Additional explanations to water management principles, illustrated in FIG. 3 and FIG. 4, are that the pressure difference adjusting process can be a pulsed or continuous process used in either water supplying direction, as shown in FIG. 3, or water removing direction, as shown in FIG. 4, upon different needs in fuel cell operations. 

1. A fuel cell constructed with proton exchange membrane (PEM) with catalyst layers on both sides, gas diffusion layers of porous materials, locally impregnated with water transferring materials placed on top of said catalyst layers, water damming layers of porous material, placed locally on said gas diffusion layers, treated with water transferring materials, and single layer bipolar plates functioned as cathode on one side and as anode on the other, installed on top of said gas diffusion layers with said damming layer sandwiched in between, having flow channels made on one side for oxidant flows and flow channels on the same side for water flows of cooling, hydration, humidification and exhaust, having flow channels made on the other side for hydrogen rich fuel flows and flow channels on the same side for water flows of cooling, hydration, humidification and exhaust.
 2. The fuel cell as claimed in claim 1 wherein said single layer bipolar plates have one side as cathode structured with flows channels for oxidant flows and water flows of cooling, hydration, humidification and exhaust, where said channels for oxidant and said channels for water are evenly spaced and segregated, and open or partially open connected onto said damming layers and gas diffusion layers by compression with a prepared rough or scraggy contacting surfaces to make contact gaps controllable for water entrance and exit by pressure difference.
 3. The fuel cell as claimed in claim 1 wherein said single layer bipolar plates have one side as anode structured with flows channels for hydrogen rich fuel flows and water flows of cooling, hydration, humidification and exhaust, where said channels for fuel and said channels for water are evenly spaced and segregated, and open or partially open connected onto said damming layers and gas diffusion layers by compression with a prepared rough or scraggy contacting surfaces to make contact gaps controllable for water entrance and exit by pressure difference.
 4. The fuel cell as claimed in claim 1 wherein said gas diffusion layers are made of electrically conductive porous materials, treated with hydrophobic materials as reactant and water flow paths, also locally treated with water transferring materials functioned as water transferring passages for hydrating said membrane, humidifying oxidant flows on one side and fuel flows on the other side, and improving cell cooling, compressed on top by said plates with a controlled contact gaps in between for water entrance and exit by pressure difference.
 5. The fuel cell as claimed in claim 1 wherein said water damming layers are made of porous materials and treated with water transferring materials functioned as a water transferring passage and flow controlling gate to manage proper amount of water for hydrating said membrane, humidifying oxidant and fuel flows, and also act as exhaust gates for water removal by pressure difference.
 6. A fuel cell constructed with proton exchange membrane (PEM) with catalyst layers on both sides, gas diffusion layers of porous materials, water damming layers of porous material, placed locally on said gas diffusion layers, treated with water transferring materials, and single layer bipolar plates functioned as cathode on one side and as anode on the other, installed on top of said gas diffusion layers with said damming layer sandwiched in between, having flow channels made on one side for hydrogen rich fuel flows, having flow channels made on the other side for oxidant flows and flow channels on the same side for water flows of cooling, hydration, humidification and exhaust.
 7. The fuel cell as claimed in claim 6 wherein said single layer bipolar plates have one side as cathode structured with flows channels for oxidant flows and water flows of cooling, hydration, humidification and exhaust, where said channels for oxidant and said channels for water are evenly spaced and segregated, and open or partially open connected onto said damming layers and gas diffusion layers by compression with a prepared rough or scraggy contacting surfaces to make contact gaps controllable for water entrance and exit by pressure difference, while on the other side of said plate flow channels are structured as anode for hydrogen rich fuel flows.
 8. The fuel cell as claimed in claim 6 wherein said gas diffusion layers are made of electrically conductive porous materials, treated with hydrophobic materials as reactant and water flow paths, compressed on top by said plates with a controlled contact gaps in between for water entrance and exit by pressure difference.
 9. The fuel cell as claimed in claim 6 wherein said water damming layers are made of porous materials and treated with water transferring materials functioned as a water transferring passage and flow controlling gate to manage proper amount of water for hydrating said membrane, humidifying oxidant and fuel flows, and also act as exhaust gates for water removal by pressure difference.
 10. A fuel cell constructed with proton exchange membrane (PEM) with catalyst layers on both sides, gas diffusion layers of electrically conductive porous materials, locally treated with water transferring materials, and single layer bipolar plates functioned as cathode on one side and as anode on the other, installed on top of said gas diffusion layers with said damming layer sandwiched in between, having flow channels made on one side for oxidant flows, having flow channels made on the other side for hydrogen rich fuel flows and flow channels on the same side for water flows of cooling, hydration, humidification and exhaust.
 11. The fuel cell as claimed in claim 10 wherein said single layer bipolar plates have one side as anode structured with flows channels for hydrogen rich fuel flows and water flows of cooling, hydration, humidification and exhaust, where said channels for fuel and said channels for water are evenly spaced and segregated, and open or partially open connected onto said damming layers and gas diffusion layers by compression with a prepared rough or scraggy contacting surfaces to make contact gaps controllable for water entrance and exit by pressure difference, while on the other side of said plate flow channels are structured as cathode for oxidant flows.
 12. The fuel cell as claimed in claim 10 wherein said gas diffusion layers are made of electrically conductive porous materials, treated with hydrophobic materials as reactant and water flow paths, also locally treated with water transferring materials functioned as water transferring passages for hydrating said membrane, humidifying oxidant flows on one side and fuel flows on the other side, and improving cell cooling, compressed on top by said plates with a controlled contact gaps in between for water entrance and exit by pressure difference. 